smss.exe is a application which is most likely NOT a virus or malware. So, if smss.exe is on your system, it is most likely ok, and will NOT be a cause for concern. Even if your PC is virus-free, it is still recommended to use a well-known antivirus with a good track record, in order to yourself your PC against potential security problems.
Usually, this application is located in C:\WINDOWS\System32\smss.exe.
The MD5 checksum for this program is f3dc4781c85bf8cb5716d5086511802b.
This program is NOT a Windows service. This is very good.
smss.exe appears to have something to do with Windows SFC (System File Checker) or Windows File Protection.
64-bit code has been detected. This application can put to good use the full power of a modern computer cpu.
smss.exe has a digital signature. Today most serious programs are digitally signed.
The digital signature extracted from smss.exe verifies as ok. This is excellent.
Digitally signed by: Microsoft Windows Publisher
Certificate's issuer name: Microsoft Windows Production PCA 2011
This program does NOT have an uninstall command set up in registry.